Resource Type

Journal Article 9

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2022 1

2021 2

2020 2

2015 2

2011 1

Keywords

acetylene 4

palladium 3

selective hydrogenation 3

ethylene 2

Acetylene semi-hydrogenation 1

Electronic effects 1

H2 pulse chemisorption 1

HAADF-STEM 1

Pd local environment 1

Pd/CeO2 1

Reaction kinetics 1

Support effects 1

acetylene hydrochlorination 1

acetylene hydrogenation 1

acetylene/carbon dioxide separation 1

adsorption 1

anion-pillared hybrid material 1

bimetallic 1

catalysts 1

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Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 2,   Pages 142-153 doi: 10.1007/s11705-015-1516-4

Abstract: Recent advances with Pd containing catalysts for the selective hydrogenation of acetylene are describedorganic modifiers such as diphenylsulfide are thought to create a surface template effect which favours acetylene

Keywords: acetylene     ethylene     selective hydrogenation     palladium     bimetallic    

Selective hydrogenation of acetylene over Pd/CeO

Kai Li, Tengteng Lyu, Junyi He, Ben W. L. Jang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 929-936 doi: 10.1007/s11705-019-1912-2

Abstract: Five hundred ppm Pd/CeO catalyst was prepared and evaluated in selective hydrogenation of acetylene

Keywords: selective hydrogenation     acetylene     Pd/CeO2     strong interaction    

Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1031-1059 doi: 10.1007/s11705-021-2113-3

Abstract: Unfortunately, during naphtha cracking to produce ethylene, there are instances of acetylene presenceThis review provides a holistic view of the recent reports on the selective hydrogenation of acetyleneThe specific role(s) that each process parameter plays to achieve high acetylene conversion and ethyleneExtensive reports suggest that acetylene adsorption occurs through an active single-site mechanism ratherAn increase in the reaction temperature affords high acetylene conversion and ethylene selectivity to

Keywords: selectivity     hydrogenation     acetylene     ethylene     palladium    

Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

Frontiers of Chemical Science and Engineering   Pages 1616-1622 doi: 10.1007/s11705-022-2183-x

Abstract: Adsorptive separation of acetylene/carbon dioxide mixtures by porous materials is an important and challengingHere, remarkable acetylene/carbon dioxide separation featuring a high dynamic breakthrough capacity foracetylene (4.3 mmol·g–1) as well as an ultralow acetylene regeneration energy (29.5 kJ·molclusters through hydrogen bonds and intermolecular interactions, which afforded a high acetylene capacity(8.3 mmol·g–1) and high acetylene/carbon dioxide uptake ratio (1.9) at 298 K and 1 bar.

Keywords: adsorption     acetylene/carbon dioxide separation     dynamic capacity     anion-pillared hybrid material    

to ‘‘Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene Corrigendum

Yueqiang Cao, Xiaohu Ge, Yurou Li, Rui Si, Zhijun Sui, Jinghong Zhou, Xuezhi Duan, Xinggui Zhou

Engineering 2021, Volume 7, Issue 5,   Pages 701-701 doi: 10.1016/j.eng.2021.04.001

Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene Article

Yueqiang Cao,   Xiaohu Ge,   Yurou Li,   Rui Si,   Zhijun Sui,   Jinghong Zhou,   Xuezhi Duan,   Xinggui Zhou

Engineering 2021, Volume 7, Issue 1,   Pages 103-110 doi: 10.1016/j.eng.2020.06.023

Abstract:

In this study, the support effects on the Pd-catalyzed semi-hydrogenation of acetylene have been investigatedlocal environment, containing subsurface carbon atoms, that produces positive geometric effects on the acetylene

Keywords: Acetylene semi-hydrogenation     Reaction kinetics     Support effects     Electronic effects     Pd local environment    

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 4,   Pages 514-520 doi: 10.1007/s11705-011-1114-z

Abstract: manufactured industrially via the dehydrochlorination of dichloroethane or the hydrochlorination of acetyleneCurrently PVC production through the acetylene hydrochlorination method accounts for about 70% of the, the industrial production of VCM utilizes a mercuric chloride catalyst to promote the reaction of acetyleneHence, for China, it is necessary to explore environmental friendly non-mercury catalysts for acetylenehydrochlorination as well as high efficiency novel reactors, with the aim of sustainable PVC production via the acetylene-based

Keywords: polyvinyl chloride     vinyl chloride monomer     acetylene hydrochlorination     non-mercury catalysts     green chemical    

of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene

Xinxiang Cao,Arash Mirjalili,James Wheeler,Wentao Xie,Ben W.-L. Jang

Frontiers of Chemical Science and Engineering 2015, Volume 9, Issue 4,   Pages 442-449 doi: 10.1007/s11705-015-1547-x

Abstract: Pd-Cu bimetallic catalysts with less than 1 wt-% Cu and ca. 0.03 wt-% Pd for selective hydrogenation of acetyleneCatalytic tests indicated that when the conversion of acetylene was above 99%, the selectivity of ethylene

Keywords: H2 pulse chemisorption     palladium-copper bimetallic catalyst     single atom alloy     acetylene hydrogenation    

Preparation and investigation of Pd doped Cu catalysts for selective hydrogenation of acetylene

Xinxiang Cao, Tengteng Lyu, Wentao Xie, Arash Mirjalili, Adelaide Bradicich, Ricky Huitema, Ben W.-L. Jang, Jong K. Keum, Karren More, Changjun Liu, Xiaoliang Yan

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 522-533 doi: 10.1007/s11705-019-1822-3

Abstract: impregnation (CSI) and modified sequential impregnation (MSI) of Cu and Pd for selective hydrogenation of acetylene

Keywords: copper     palladium     catalysts     acetylene     selective hydrogenation    

Title Author Date Type Operation

Recent advances in selective acetylene hydrogenation using palladium containing catalysts

Alan J. McCue, James A. Anderson

Journal Article

Selective hydrogenation of acetylene over Pd/CeO

Kai Li, Tengteng Lyu, Junyi He, Ben W. L. Jang

Journal Article

Catalysis of semihydrogenation of acetylene to ethylene: current trends, challenges, and outlook

Journal Article

Efficient acetylene/carbon dioxide separation with excellent dynamic capacity and low regeneration energy

Journal Article

to ‘‘Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene

Yueqiang Cao, Xiaohu Ge, Yurou Li, Rui Si, Zhijun Sui, Jinghong Zhou, Xuezhi Duan, Xinggui Zhou

Journal Article

Structural and Kinetics Understanding of Support Effects in Pd-Catalyzed Semi-Hydrogenation of Acetylene

Yueqiang Cao,   Xiaohu Ge,   Yurou Li,   Rui Si,   Zhijun Sui,   Jinghong Zhou,   Xuezhi Duan,   Xinggui Zhou

Journal Article

Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts

Jinli ZHANG, Nan LIU, Wei LI, Bin DAI

Journal Article

of the preparation methodologies of Pd-Cu single atom alloy catalysts for selective hydrogenation of acetylene

Xinxiang Cao,Arash Mirjalili,James Wheeler,Wentao Xie,Ben W.-L. Jang

Journal Article

Preparation and investigation of Pd doped Cu catalysts for selective hydrogenation of acetylene

Xinxiang Cao, Tengteng Lyu, Wentao Xie, Arash Mirjalili, Adelaide Bradicich, Ricky Huitema, Ben W.-L. Jang, Jong K. Keum, Karren More, Changjun Liu, Xiaoliang Yan

Journal Article